Time-resolved micelle-stabilized room-temperature phosphorimetry for simultaneous determination of gallium and indium
Identifieur interne : 000346 ( Main/Exploration ); précédent : 000345; suivant : 000347Time-resolved micelle-stabilized room-temperature phosphorimetry for simultaneous determination of gallium and indium
Auteurs : RBID : ISTEX:604_1991_Article_BF01309026.pdfEnglish descriptors
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Abstract
Ga(III) and In(III) react with 7-iodo-hydroxyquinoline-5-sulphonic acid (Ferron) in the presence of CTAB micelles, forming complexes which exhibit analytically useful room-temperature phosphorescence (RTP). The RTP features of the two complexes are similar and the RTP spectra overlap. However, there is sufficient difference between the two phosphorescence decay rates for both metals to be determined by time-resolved room-temperature phosphorimetry.
DOI: 10.1007/BF01309026
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<author><name>Yi-Ming Liu</name>
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<author><name>Jose Ignacio Garcia Alonso</name>
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<author><name>Maria Rosario Fernández de la Campa</name>
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<author><name>Marta Elena Diaz Garcia</name>
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<author><name>Alfredo Sanz-Medel</name>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Gallium</term>
<term>Indium</term>
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<front><div type="abstract" xml:lang="eng">Ga(III) and In(III) react with 7-iodo-hydroxyquinoline-5-sulphonic acid (Ferron) in the presence of CTAB micelles, forming complexes which exhibit analytically useful room-temperature phosphorescence (RTP). The RTP features of the two complexes are similar and the RTP spectra overlap. However, there is sufficient difference between the two phosphorescence decay rates for both metals to be determined by time-resolved room-temperature phosphorimetry.</div>
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<abstract lang="eng">Ga(III) and In(III) react with 7-iodo-hydroxyquinoline-5-sulphonic acid (Ferron) in the presence of CTAB micelles, forming complexes which exhibit analytically useful room-temperature phosphorescence (RTP). The RTP features of the two complexes are similar and the RTP spectra overlap. However, there is sufficient difference between the two phosphorescence decay rates for both metals to be determined by time-resolved room-temperature phosphorimetry.</abstract>
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<topic>time-resolved liquid room-temperature phosphorescence</topic>
<topic>multicomponent analysis</topic>
<topic>gallium</topic>
<topic>indium</topic>
<topic>Kalman filtering</topic>
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<relatedItem type="series"><titleInfo type="abbreviated"><title>Mikrochim Acta</title>
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<titleInfo><title>Microchimica Acta</title>
<subTitle>Micro and Trance Analysis</subTitle>
<partNumber>Year: 1991</partNumber>
<partNumber>Volume: 103</partNumber>
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<topic>Analytical Chemistry</topic>
<topic>Inorganic Chemistry</topic>
<topic>Physical Chemistry</topic>
<topic>Characterization and Evaluation Materials</topic>
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